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Issue 13, 1987
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Rearrangement vs. dissociation of gaseous silicon-containing cations: a combined experimental–theoretical approach

Abstract

The dissociative ionizations of p-MeC6H4O[CH2]2SiMe3, MeCH(Cl)SiMe2Cl, and Me[CH2]2SiMe2Cl were studied in the gas phase, experimentally by using tandem mass spectrometric techniques (MS/MS) and computationally by ab initio M.O. methods, revealing a complex scheme of rearrangements that interconvert the resulting isomeric C5H13Si+ ions, including silicenium ions and α- and β-silyl substituted carbocations.

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Article type: Paper
DOI: 10.1039/C39870000989
Citation: J. Chem. Soc., Chem. Commun., 1987,0, 989-991

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    Rearrangement vs. dissociation of gaseous silicon-containing cations: a combined experimental–theoretical approach

    Y. Apeloig, M. Karni, A. Stanger, H. Schwarz, T. Drewello and G. Czekay, J. Chem. Soc., Chem. Commun., 1987, 0, 989
    DOI: 10.1039/C39870000989

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