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Issue 13, 1987
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Stabilisation of mononuclear palladium(III). The single crystal X-ray structure of the [Pd(L)2]3+ cation (L = 1,4,7-trithiacyclononane)

Abstract

Oxidation of the green [Pd(1)2]2+ cation [(1)= 1,4,7-trithiacyclononane] in 70% aqueous HClO4 affords the red [Pd(1)2]3+ cation, the single crystal X-ray structure of which shows a tetragonally distorted geometry about the PdIII centre with Pd–S(1) 2.5448(15), Pd–S(4) 2.3558(14), and Pd–S(7) 2.3692(15)Å.

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Article type: Paper
DOI: 10.1039/C39870000987
Citation: J. Chem. Soc., Chem. Commun., 1987,0, 987-988
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    Stabilisation of mononuclear palladium(III). The single crystal X-ray structure of the [Pd(L)2]3+ cation (L = 1,4,7-trithiacyclononane)

    A. J. Blake, A. J. Holder, T. I. Hyde and M. Schröder, J. Chem. Soc., Chem. Commun., 1987, 0, 987
    DOI: 10.1039/C39870000987

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