SCHEDULED MAINTENANCE
Two biogenetically possible key intermediates, from epidithiodioxopiperazines to trioxopiperazines, aurantioemestrin (1) and silvathione (2) were isolated from Emericella striata and Aspergillus silvaticus, respectively; their structure elucidation was based on their 1H and 13C n.m.r. spectra.
N. Kawahara, K. Nozawa, S. Nakajima and K. Kawai, J. Chem. Soc., Chem. Commun., 1986, 1495 DOI: 10.1039/C39860001495
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