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12-Methylisobacteriochlorins, which are important for future research on the biosynthesis of vitamin B12, have been prepared by two methods from isobacteriochlorins carrying a 12-acetic acid residue; enzymic methylation of the 12-methyl analogue of uro'gen-III has yielded the 12-methyl analogue of sirohydrochlorin.
A. R. Battersby, C. Bladon, J. Huang and S. Seo, J. Chem. Soc., Chem. Commun., 1986, 1492 DOI: 10.1039/C39860001492
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