Issue 12, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Polyhedral rearrangement of a metallacarbaborane group in a dimetal complex: transformation of a metal-bound alkylidyne ligand into a B-alkyl substituent on the carbaborane cage

Michael J. Attfield,   Judith A. K. Howard,   Alasdair N. de M. Jelfs,   Christine M. Nunn  and  F. Gordon A. Stone  

Abstract

Reaction of [N(PPh3)2][W([triple bond, length half m-dash]CR)(CO)2(η5-1,2-C2B9H9Me2)](1, R = C6H4Me-4) with [trans-PtH(acetone)(PEt3)2][BF4] affords [PtW(CO)2(PEt3)2{η6-C2B9H8(CH2R)Me2}](2), which with PMe3 or CO yields [PtW(µ-H){µ-σ,η5-C2B9H7-(CH2R)Me2}(CO)2(L)(PEt3)2](3a), L = PMe3; 3b, L = CO); the molecular structures of (2) and (3a) have been established by X-ray diffraction.

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Article information

DOI
https://doi.org/10.1039/C39860000918
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 918-920

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Polyhedral rearrangement of a metallacarbaborane group in a dimetal complex: transformation of a metal-bound alkylidyne ligand into a B-alkyl substituent on the carbaborane cage

M. J. Attfield, J. A. K. Howard, A. N. de M. Jelfs, C. M. Nunn and F. G. A. Stone, J. Chem. Soc., Chem. Commun., 1986, 918 DOI: 10.1039/C39860000918

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