Issue 19, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

The preparation of an unsaturated hydrido osmium cluster by hydrogenolysis of a cyclometallated phosphine; the X-ray structure of [Os3(CO)8(H)2(Ph2PCH2PPh2)]

Jennifer A. Clucas,   Marjorie M. Harding  and  Anthony K. Smith  

Abstract

Treatment of [Os3(CO)8(H){Ph2PCH2P(Ph)C6H4}] with H2 affords a high yield of the unsaturated cluster [Os3(CO)8(H)2-(Ph2PCH2PPh2)] which has been characterised by X-ray crystallography.

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Article information

DOI
https://doi.org/10.1039/C39850001280
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1280-1281

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The preparation of an unsaturated hydrido osmium cluster by hydrogenolysis of a cyclometallated phosphine; the X-ray structure of [Os3(CO)8(H)2(Ph2PCH2PPh2)]

J. A. Clucas, M. M. Harding and A. K. Smith, J. Chem. Soc., Chem. Commun., 1985, 1280 DOI: 10.1039/C39850001280

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