Issue 22, 1983

A new 1,2-rearrangement of carbon from sulphur to carbon in 2,2-diaryl-1,3-dithianes

Abstract

2,2-Diaryl-1,3-dithianes undergo with lithium di-isopropylamide in tetrahydrofuran a Wittig-type rearrangement to form the anions of the 2,2-diaryltetrahydrothiophene-3-thiols which are further converted into bis(2,2-diaryltetrahydrothiophen-3-yl) disulphides by treatment with aqueous ammonium chloride and after subsequent autoxidation.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 1354-1355

A new 1,2-rearrangement of carbon from sulphur to carbon in 2,2-diaryl-1,3-dithianes

H. Ikehira and S. Tanimoto, J. Chem. Soc., Chem. Commun., 1983, 1354 DOI: 10.1039/C39830001354

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