Issue 15, 1979

Reaction of dimethylsilylene with α-diketones. Formation and reaction of 1,3-dioxa-2-silacyclopent-4-enes

Abstract

Photolysis of dodecamethylcyclohexasilane (1) in biacetyl, pentane-2,3-dione, bi-n-butyryl, bi-iso-butyryl, and 3,5-di-t-butyl-o-benzoquinone gave substituted 1,3-dioxa-2-silacyclopent-4-enes, the thermal and chemical properties of which are reported.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 655-656

Reaction of dimethylsilylene with α-diketones. Formation and reaction of 1,3-dioxa-2-silacyclopent-4-enes

W. Ando and M. Ikeno, J. Chem. Soc., Chem. Commun., 1979, 655 DOI: 10.1039/C39790000655

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