The photolyses of pure pyranosiduloses (1) and (2) afford decarbonylated compounds (3), (4), and (5) in the same ratios, suggesting that they are formed via a common stabilised biradical (6).
P. M. Collins, P. Gupta and R. Iyer, J. Chem. Soc. D, 1970, 1261 DOI: 10.1039/C29700001261
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