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Issue 19, 1970
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Photochemical decarbonylation of cyclic ketones in solution: evidence for a biradical intermediate in the pyranosidulose–furanoside conversion

Abstract

The photolyses of pure pyranosiduloses (1) and (2) afford decarbonylated compounds (3), (4), and (5) in the same ratios, suggesting that they are formed via a common stabilised biradical (6).

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Article information


J. Chem. Soc. D, 1970, 1261-1262
Article type
Paper

Photochemical decarbonylation of cyclic ketones in solution: evidence for a biradical intermediate in the pyranosidulose–furanoside conversion

P. M. Collins, P. Gupta and R. Iyer, J. Chem. Soc. D, 1970, 1261
DOI: 10.1039/C29700001261

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