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Issue 19, 1970
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Asymmetric isomerization of racemic α-olefins by titanium tetra-(–)-menthoxide–tri-isobutylaluminium

Abstract

The homogeneous catalytic system obtained from AlBu3i and an optically active titanium alkoxide [titanium tetra-(–)-menthoxide] effects asymmetric isomerization of racemic α-olefins into Z- and E-2-olefins, whereas no asymmetric transformation occurs in the hydrogenation.

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Article information


J. Chem. Soc. D, 1970, 1260-1261
Article type
Paper

Asymmetric isomerization of racemic α-olefins by titanium tetra-(–)-menthoxide–tri-isobutylaluminium

C. Carlini, D. Politi and F. Ciardelli, J. Chem. Soc. D, 1970, 1260
DOI: 10.1039/C29700001260

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