A Li-biphenyl (BP) anolyte is adopted in a 2.7 V Li-BP–LiI3 nonaqueous redox flow battery (NRFB). The Fe–N–C MOF separator mitigates cross-contamination and enhances LiI3 reduction, as confirmed by DFT. The NRFB exhibits 80 Ah L−1 capacity and 96% retention over 100 cycles, offering a pathway for achieving high-voltage and high-stability.
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C. Shao, J. Li, Y. Liu and H. Chen, Chem. Commun., 2025, 61, 17392 DOI: 10.1039/D5CC04436G
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