Issue 9, 2024

Solvent dependent hierarchical dual helicity in a fused [4]carbohelicene/quinoline oligoamide foldamer

Abstract

Two classes of helical motif, namely a [4]carbohelicene and an aromatic oligoamide foldamer, were fused to form a hybrid molecular construct in which their helical axes are parallel. Depending on the solvent, the [4]carbohelicene can bias the dynamic screw sense of the aromatic oligoamide with a reverse handedness.

Graphical abstract: Solvent dependent hierarchical dual helicity in a fused [4]carbohelicene/quinoline oligoamide foldamer

Supplementary files

Article information

Article type
Research Article
Submitted
19 Feb 2024
Accepted
17 Mar 2024
First published
18 Mar 2024
This article is Open Access
Creative Commons BY-NC license

Org. Chem. Front., 2024,11, 2632-2637

Solvent dependent hierarchical dual helicity in a fused [4]carbohelicene/quinoline oligoamide foldamer

R. Borges-Anastácio, K. Moreno, E. Merlet, T. Buffeteau, B. Kauffmann, N. McClenaghan, Y. Ferrand and C. Olivier, Org. Chem. Front., 2024, 11, 2632 DOI: 10.1039/D4QO00320A

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