Synthesis of porphyrin(2.1.2.1) Pd(II) complexes embedded with various π units and their singlet oxygen generation capacity

Xiaojuan Lv; Feng Chen; Mingbo Zhou; Tao Zhang; Fengxian Qiu; Songlin Xue

doi:10.1039/D4DT01749H

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Synthesis of porphyrin(2.1.2.1) Pd(ii) complexes embedded with various π units and their singlet oxygen generation capacity†‡

Xiaojuan Lv,^a Feng Chen,*^a Mingbo Zhou,^b Tao Zhang,

^a Fengxian Qiu

^a and Songlin Xue

*^ab

Author affiliations

* Corresponding authors

^a School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, China
E-mail: fengjchen@ujs.edu.cn, slxue@ujs.edu.cn

^b Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha, Hunan 410081, China

Abstract

Novel porphyrin(2.1.2.1) Pd(II) complexes with various aromatic π rings (benzo, naphthalene and thiophene) embedded between dipyrrin units have been synthesized. Their molecular structures and optical and electronic properties were confirmed and fully investigated. These Pd(II) complexes showed moderate to good capacity of singlet oxygen generation under light irradiation.

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Article information

DOI: https://doi.org/10.1039/D4DT01749H
Article type: Paper
Submitted: 15 Jun 2024
Accepted: 27 Jul 2024
First published: 02 Aug 2024

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Dalton Trans., 2024,53, 14433-14437

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Synthesis of porphyrin(2.1.2.1) Pd(II) complexes embedded with various π units and their singlet oxygen generation capacity

X. Lv, F. Chen, M. Zhou, T. Zhang, F. Qiu and S. Xue, Dalton Trans., 2024, 53, 14433 DOI: 10.1039/D4DT01749H

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Dalton Transactions

Synthesis of porphyrin(2.1.2.1) Pd(ii) complexes embedded with various π units and their singlet oxygen generation capacity†‡

Abstract

Supplementary files

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Synthesis of porphyrin(2.1.2.1) Pd(II) complexes embedded with various π units and their singlet oxygen generation capacity

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