Issue 6, 2024

Photo-induced valence tautomerism and polarization switching in mononuclear cobalt complexes with an enantiopure chiral ligand

Abstract

Light-induced polarization switchable molecular materials have attracted attention for decades owing to their potential remote manipulation and ultrafast responsiveness. Here we report a valence tautomeric (VT) complex with an enantiopure chiral ligand. By a suitable choice of counter anions, a significant improvement in photoconversion has been demonstrated, leading to novel photo-responsive polarization switching materials.

Graphical abstract: Photo-induced valence tautomerism and polarization switching in mononuclear cobalt complexes with an enantiopure chiral ligand

Supplementary files

Article information

Article type
Paper
Submitted
22 Nov 2023
Accepted
31 Dec 2023
First published
02 Jan 2024
This article is Open Access
Creative Commons BY license

Dalton Trans., 2024,53, 2512-2516

Photo-induced valence tautomerism and polarization switching in mononuclear cobalt complexes with an enantiopure chiral ligand

W. Xu, Y. Huang, W. Zheng, S. Su, S. Kanegawa, S. Wu and O. Sato, Dalton Trans., 2024, 53, 2512 DOI: 10.1039/D3DT03915C

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