Linker engineering toward near-infrared-I emissive metal–organic frameworks for amine detection

Abstract

Herein, organic linker-based near-infrared-I (NIR-I) emissive metal–organic frameworks (MOFs), with a maximum emission peak at 741 nm, were synthesized via linker engineering. By integration of stronger acceptor and donor groups into one linker, a significant bathochromic-shift is realized. This MOF exhibits great selectivity and sensitivity for aniline and p-phenylenediamine detection. This finding provides new insights into the rational design of NIR-MOFs for sensing and related applications.