Issue 15, 2023
From the journal:

Dalton Transactions

Linker permethylation as a means to foster valence tautomerism and thwart dimerization in ferrocenyl-triarylmethylium cations†

Moritz Nau,a   Larissa A. Casper,a   Gernot Haug,a   Michael Linseis,a   Serhiy Demeshkob  and  Rainer F. Winter ORCID logo *a  

* Corresponding authors

a Fachbereich Chemie, Universität Konstanz, Universitätsstraße 10, 78457 Konstanz, Germany
E-mail: rainer.winter@uni-konstanz.de

b Institut für Anorganische Chemie, Georg-August-Universität Göttingen, Tammanstraße 4, 37077 Göttingen, Germany

Abstract

Permethylation of the phenylene linker in a cationic ferrocenyl-phenylthioxanthylium dyad increases the amount of the diradical ferrocenium thioxanthyl radical valence tautomer and aids in supressing dimerization of the latter and of the one-electron reduced neutral radical.

Graphical abstract: Linker permethylation as a means to foster valence tautomerism and thwart dimerization in ferrocenyl-triarylmethylium cations

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Article information

DOI
https://doi.org/10.1039/D3DT00857F
Article type
Communication
Submitted
21 Mar 2023
Accepted
27 Mar 2023
First published
28 Mar 2023
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2023,52, 4674-4677

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Linker permethylation as a means to foster valence tautomerism and thwart dimerization in ferrocenyl-triarylmethylium cations

M. Nau, L. A. Casper, G. Haug, M. Linseis, S. Demeshko and R. F. Winter, Dalton Trans., 2023, 52, 4674 DOI: 10.1039/D3DT00857F

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