We report the synthesis and characterization of ionic compounds [(thf)4YbI]2[Ge9(Hyp)3]2 (1) and [(thf)5LnI]4[Ge9(Hyp)3]4 (Ln = Eu (2), Sm (3)), (Hyp = Si(SiMe3)3). All compounds were examined by UV-Vis spectroscopy and a blue luminescence of Eu2+ was found. The solid state magnetic measurements of complexes 2 and 3 confirmed the presence of divalent lanthanides.
S. V. Klementyeva, C. Schrenk, M. Zhang and M. M. Khusniyarov, Dalton Trans., 2023, 52, 4669 DOI: 10.1039/D3DT00578J
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