Issue 73, 2023

Photoinduced electron transfer between a noble-metal-free [Mo6I8Cl6]2− cluster and polyoxometalates

Abstract

Evidence for photoinduced intermolecular electron transfer from the excited state of the [Mo6I8Cl6]2− electron-rich cluster to polyoxometalates (POMs) is reported. We demonstrate that the global charge density of POMs affects the efficiency of electron transfer. This work paves the way for the rational design of photocatalytic systems using cluster-based complexes as robust noble-metal-free photosensitizers.

Graphical abstract: Photoinduced electron transfer between a noble-metal-free [Mo6I8Cl6]2− cluster and polyoxometalates

Supplementary files

Article information

Article type
Communication
Submitted
11 Jul 2023
Accepted
24 Jul 2023
First published
07 Aug 2023

Chem. Commun., 2023,59, 10988-10991

Photoinduced electron transfer between a noble-metal-free [Mo6I8Cl6]2− cluster and polyoxometalates

A. Fatima, Y. Smortsova, C. Falaise, N. Leclerc, M. Haouas, E. Cadot, S. Cordier, Y. Molard, T. Pino, C. Dablemont, R. Méallet, K. Steenkeste and M. Ha-Thi, Chem. Commun., 2023, 59, 10988 DOI: 10.1039/D3CC03334A

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