Selective photoelectrocatalytic oxidation of 3-methylpyridine to vitamin B3 by WO3 decorated nanotube-structured TiO2

Abstract

Nanotube-structured TiO₂ electrodes on Ti plates were formed in ethylene glycol solution by the anodic oxidation method applied for different times and calcined at 500 °C. Different amounts of WO₃ were decorated on the nanotube surfaces electrochemically. The electrodes were characterized, and the effects of the nanotube length on the Ti plate, decorated WO₃ amount, electrolyte concentration, applied potential, and type of radiation source on the oxidation of 3-methylpyridine were investigated, together with the product distribution/selectivity. In a photoelectrocatalytic system, the vitamin B₃ yield increased significantly (ca. 17 fold) under UVA by decorating nanotube-structured TiO₂ with WO₃, whilst low reaction rates and no products were found under Vis irradiation, as only unselective photolytic reactions occurred. This unexpected result was clarified for the first time in the literature.