Issue 26, 2023

Ba4Ni3F14·H2O: a ferrimagnetic compound with a staircase kagomé lattice

Abstract

A new crystalline fluoride Ba4Ni3F14·H2O was found to exhibit a rare S = 1 staircase kagomé lattice built by Ni2+ ions. Magnetic measurements indicate a ferrimagnetic transition at ∼28 K, while 1/3 plateau can be observed from the magnetization curve. We suggest that the hydrogen-bond interactions of O–H⋯F pathways may play an important role for magnetic properties of the system.

Graphical abstract: Ba4Ni3F14·H2O: a ferrimagnetic compound with a staircase kagomé lattice

Supplementary files

Article information

Article type
Communication
Submitted
19 Dec 2022
Accepted
07 Mar 2023
First published
07 Mar 2023

Chem. Commun., 2023,59, 3870-3873

Ba4Ni3F14·H2O: a ferrimagnetic compound with a staircase kagomé lattice

Y. Wang, Z. Zhao, M. Cui and Z. He, Chem. Commun., 2023, 59, 3870 DOI: 10.1039/D2CC06906G

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