Arsolyl-supported intermetallic dative bonding†
Ryan M.
Kirk 
a
and
Anthony F.
Hill
*a
a
and
Anthony F.
Hill
*a
Abstract
The first examples of late transition metal η5-arsolyls 
(L = CO, P(OMe)3; R = Ph, Me, Et, SiMe3; R′ = Ph, H, Me, Et, Me) serve as ditopic donors to extraneous metal centres (M = PtII, AuI, HgII) through both conventional As → M and polar-covalent (dative) Co → M interactions.
- This article is part of the themed collection: 2022 Chemical Science HOT Article Collection
Please wait while we load your content...
