Bimetallic nickel/manganese phosphate–carbon nanofiber electrocatalyst for the oxidation of formaldehyde in alkaline medium

Abstract

The development of earth-abundant transition metal-based catalysts, supported by a conductive carbonaceous matrix, has received great attention in the field of conversion of formaldehyde derivatives into toxic-free species. Herein, we report a comprehensive investigation of bimetallic electrocatalyst activity towards the electrooxidation of formaldehyde. The bimetallic phosphate catalyst is prepared by co-precipitation of Ni and Mn phosphate precursors using a simple reflux approach. Then the bimetallic catalyst is produced by mixing the Ni/Mn with carbon fibres (CNFs). The structural properties and crystallinity of the catalyst were investigated by using several techniques, such as scanning electron microscopy, X-ray diffraction, energy-dispersive X-ray spectroscopy, and Brunauer Emmett−Teller theory. The system performance was studied under potentiostatic conditions. Some theoretical thermodynamic and kinetic models were applied to assess the system performance. Accordingly, key electrochemical parameters, including surface coverage (Γ) of active species, charge transfer rate (k_s), diffusion coefficient of the formaldehyde (D), and catalytic rate constant (k_cat) were calculated at Γ = 1.690 × 10⁻⁴ mmol cm⁻², k_s = 1.0800 s⁻¹, D = 1.185 × 10⁻³ cm² s⁻¹ and k_cat = 1.08 × 10⁵ cm³ mol⁻¹ s⁻¹. These findings demonstrate the intrinsic electrocatalytic activity of formaldehyde electrooxidation on nickel/manganese phosphate- CNFs in alkaline medium.