Selective catalytic reduction of NOx by low-temperature NH3 over MnxZr1 mixed-oxide catalysts

Abstract

Mn_xZr₁ series catalysts were prepared by a coprecipitation method. The effect of zirconium doping on the NH₃-SCR performance of the MnO_x catalyst was studied, and the influence of the calcination temperature on the catalyst activity was explored. The results showed that the Mn₆Zr₁ catalyst exhibited good NH₃-SCR activity when calcined at 400 °C. When the reaction temperature was 125–250 °C, the NO_x conversion rate of Mn₆Zr₁ catalyst reached more than 90%, and the optimal conversion efficiency reached 97%. In addition, the Mn₆Zr₁ catalyst showed excellent SO₂ and H₂O resistance at the optimum reaction temperature. Meanwhile, the catalysts were characterized. The results showed that the morphology of the MnO_x catalyst was significantly changed, whereby as the proportion of Mn⁴⁺ and O_α species increased, the physical properties of the catalyst were improved. In addition, both Lewis acid sites and Brønsted acid sites existed in the Mn₆Zr₁ catalyst, which reduced the reduction temperature of the catalyst. In summary, zirconium doping successfully improved the NH₃-SCR performance of MnO_x.