Oligosaccharides elevate the gelatinization temperature of wheat starch more than sucrose, paving the way for their use in reduced sugar starch-based formulations

Abstract

The gelatinization of wheat starch influences the final structure and texture of baked goods. Sucrose effectively elevates the gelatinization temperature (T_gel) of starch more than many sweeteners, and maintaining a higher T_gel has been a challenge while reducing the amount of sucrose in baked goods. The objective of this study was to quantify the effects of 14 different oligosaccharides (OS: maltose, isomaltulose, kestose, maltotriose, melezitose, raffinose, stachyose, a fructo-OS, a galacto-OS, an isomalto-OS, lactosucrose, a xylo-OS, and two glucose-based dextrins), allulose, and sucrose at different concentrations (0 to 60% w/w) on the T_gel of wheat starch using DSC, and to determine which OS physicochemical properties best explained the T_gel results. OS type and concentration significantly altered T_gel. Many OS elevated the T_gel as much as or more than sucrose at the same solution concentrations, while allulose did not. The onset T_gel in water was 60 °C, in 60% sucrose was 96 °C, in 60% allulose was 80 °C, and T_gel increased up to 107–108 °C in 60% fructo-OS and Nutriose® solutions. The effects of OS on T_gel correlated most strongly (r > 0.95) with two OS solution parameters: the solvent effective volume fraction (ϕ_w,eff, related to solute intermolecular hydrogen bond density) and solution viscosity, to a lesser extent with solution water activity, and not to the glass transition temperature of the OS. Based on T_gel elevation, many of the OS are promising sucrose replacements in baked goods, which could facilitate their use in desirable higher fiber, reduced sugar starch-based baked product formulations.