Issue 43, 2022

A semiconducting uranium–organic framework based on a tetrathiafulvalene derivative

Abstract

A rare case of semiconducting actinide-based metal–organic framework SCU-125 was designed and synthesized. As a result of the lack of two coordination sites in the plane of the tetrathiafulvalene tetrabenzoate (TTFTB) molecule, a defective kgd network was formed. The electrical conductivity of SCU-125 was measured to be 2.2(2) × 10−7 S cm−1 at 25 °C ± 2 °C.

Graphical abstract: A semiconducting uranium–organic framework based on a tetrathiafulvalene derivative

Supplementary files

Article information

Article type
Communication
Submitted
05 Dec 2021
Accepted
13 Sep 2022
First published
30 Sep 2022

Dalton Trans., 2022,51, 16448-16452

A semiconducting uranium–organic framework based on a tetrathiafulvalene derivative

F. Zhai, H. Li, D. Gui, C. Xia, Z. Chai and S. Wang, Dalton Trans., 2022, 51, 16448 DOI: 10.1039/D1DT04099E

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