Regioisomeric core–shell cuprofullerene C60@Cu24

You-Shi Guo; Shun-Ze Zhan; Jia-Jing Zhong; Weigang Lu; Seik Weng Ng; Dan Li

doi:10.1039/D2CC00683A

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Regioisomeric core–shell cuprofullerene C₆₀@Cu₂₄†

You-Shi Guo,

^a Shun-Ze Zhan,

*^ab Jia-Jing Zhong,

^a Weigang Lu,

^b Seik Weng Ng

^c and Dan Li

*^b

Author affiliations

* Corresponding authors

^a Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou 515063, P. R. China
E-mail: szzhan@stu.edu.cn

^b College of Chemistry and Materials Science, and Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, P. R. China
E-mail: danli@jnu.edu.cn

^c UCSI University, Cheras, Kuala Lumpur, Malaysia

Abstract

The controlled synthesis of high-nuclear regioisomeric core–shell exohedral metallofullerenes (ExMFs) is challenging. Herein, we demonstrated the synthesis of regioisomeric core–shell cuprofullerene C₆₀@Cu^I₂₄ and its 3-D coordination polymer using heteroleptic ligands, realizing high-nuclear regioisomeric ExMFs and a polymeric ExMF structure.

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Article information

DOI: https://doi.org/10.1039/D2CC00683A
Article type: Communication
Submitted: 08 Feb 2022
Accepted: 01 Apr 2022
First published: 04 Apr 2022

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Chem. Commun., 2022,58, 5470-5473

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Regioisomeric core–shell cuprofullerene C₆₀@Cu₂₄

Y. Guo, S. Zhan, J. Zhong, W. Lu, S. W. Ng and D. Li, Chem. Commun., 2022, 58, 5470 DOI: 10.1039/D2CC00683A

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