Issue 43, 2021

Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex

Abstract

N-Dealkylation of amines by metal oxo intermediates (M[double bond, length as m-dash]O) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N-dealkylation of various alkylamines by a luminescent osmium(VI) nitrido complex induced by visible light.

Graphical abstract: Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex

Supplementary files

Article information

Article type
Edge Article
Submitted
10 Aug 2021
Accepted
08 Oct 2021
First published
09 Oct 2021
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2021,12, 14494-14498

Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(VI) nitrido complex

J. Xiang, M. Peng, Y. Pan, L. Luo, S. Cheng, X. Jin, S. Yiu, W. Man, C. Ko, K. Lau and T. Lau, Chem. Sci., 2021, 12, 14494 DOI: 10.1039/D1SC04369B

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements