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Issue 22, 2021
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Synthesis and properties of helically-folded poly(arylenediethynylene)s

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Abstract

Aryl-based helical foldamers with diacetylene linkers are not only capable of providing physically large diameter cavities, but can also showcase a variety of properties, such as structural transformation, that the corresponding foldamers with simple acetylene linkers cannot achieve. Here, we have developed helical foldamers based on poly(arylene diethynylene)s (poly-ArDEs), in which each aryl group is connected by diacetylene linkers. The poly-ArDEs with naphthalene, pyrene and pyridine as a central aryl group each expressed unique properties. The foldamers incorporating naphthalene and pyrene stabilized the helical folding in a variety of solvents. In addition, the concentration-dependent emission by the pyrene polymer was completely different from that of the monomer due to its folded three-dimensional structure. The pyridine-based polymer showed unexpected solvent dependence and stimuli responsiveness, suggesting possible applications in sensing. These properties were elucidated in detail by UV–Vis absorption, fluorescence, and circular dichroism (CD) spectra, molecular dynamics calculations, and titration experiments.

Graphical abstract: Synthesis and properties of helically-folded poly(arylenediethynylene)s

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Article information


Submitted
02 Feb 2021
Accepted
09 May 2021
First published
10 May 2021

Polym. Chem., 2021,12, 3290-3298
Article type
Paper

Synthesis and properties of helically-folded poly(arylenediethynylene)s

M. Toya, H. Ito and K. Itami, Polym. Chem., 2021, 12, 3290
DOI: 10.1039/D1PY00144B

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