Allylation and propargylation of aldehydes mediated by in situ generated zinc from the redox couple of Al and ZnCl2 in 2N HCl

Bibhas Mondal; Utpal Adhikari; Partha Pratim Hajra; Ujjal Kanti Roy

doi:10.1039/D1NJ00978H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Allylation and propargylation of aldehydes mediated by in situ generated zinc from the redox couple of Al and ZnCl₂ in 2N HCl†

Bibhas Mondal,^ab Utpal Adhikari,^b Partha Pratim Hajra^a and Ujjal Kanti Roy

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Kazi Nazrul University, Asansol-713340, India
E-mail: uroccu@gmail.com
Tel: +91-9732657939

^b Department of Chemistry, National Institute of Technology Durgapur, Durgapur-713209, India

Abstract

A simple one pot allylation and propargylation of aldehydes mediated by zinc(0), which is in situ generated from the redox couple of Al and ZnCl₂ in 2N HCl, is demonstrated to afford the corresponding homoallyl and homopropargyl alcohols with excellent yields.

Download options Please wait...

Supplementary files

Supplementary information PDF (2876K)

Article information

DOI: https://doi.org/10.1039/D1NJ00978H
Article type: Paper
Submitted: 26 Feb 2021
Accepted: 13 Mar 2021
First published: 15 Mar 2021

Download Citation

New J. Chem., 2021,45, 7163-7173

Permissions

Request permissions

Allylation and propargylation of aldehydes mediated by in situ generated zinc from the redox couple of Al and ZnCl₂ in 2N HCl

B. Mondal, U. Adhikari, P. P. Hajra and U. K. Roy, New J. Chem., 2021, 45, 7163 DOI: 10.1039/D1NJ00978H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

New Journal of Chemistry