Issue 24, 2021

Limonene dioxide as a building block for 100% bio-based thermosets

Abstract

This study valorises the benign epoxidation of (R)-(+)-limonene to generate novel bio-resourced limonene dioxide monomers. Without additional steps of separation or functionalization, the racemic limonene dioxide was cured with glutaric and dimethylglutaric anhydrides leading to thermosets with a high Tg (∼98 °C) and good mechanical properties (σ = 27 MPa; ε = 3.5%; E = 1150 MPa; E′ = 1650 MPa, Shore D = 78).

Graphical abstract: Limonene dioxide as a building block for 100% bio-based thermosets

Supplementary files

Article information

Article type
Communication
Submitted
30 Jul 2021
Accepted
13 Sep 2021
First published
14 Sep 2021

Green Chem., 2021,23, 9855-9859

Limonene dioxide as a building block for 100% bio-based thermosets

A. Mija, E. Louisy, S. Lachegur, V. Khodyrieva, P. Martinaux, S. Olivero and V. Michelet, Green Chem., 2021, 23, 9855 DOI: 10.1039/D1GC02732H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements