Issue 3, 2021

Continuous-flow step-economical synthesis of thiuram disulfides via visible-light photocatalytic aerobic oxidation

Abstract

A continuous-flow photocatalytic synthesis of the industrially important thiuram disulfides has been developed, utilizing O2 as the oxidant and Eosin Y as the photoredox catalyst. This highly atom- and step-economical method features much reduced reaction time as well as excellent product yield and purity, making it a sustainable and potentially scalable process for industrial production.

Graphical abstract: Continuous-flow step-economical synthesis of thiuram disulfides via visible-light photocatalytic aerobic oxidation

Supplementary files

Article information

Article type
Paper
Submitted
17 Dec 2020
Accepted
08 Jan 2021
First published
26 Jan 2021

Green Chem., 2021,23, 1280-1285

Continuous-flow step-economical synthesis of thiuram disulfides via visible-light photocatalytic aerobic oxidation

H. Xu, Z. Zhao, Y. Patehebieke, Q. Chen, S. Fu, S. Chang, X. Zhang, Z. Zhang and X. Wang, Green Chem., 2021, 23, 1280 DOI: 10.1039/D0GC04270F

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