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Issue 7, 2021
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Elucidating the paramagnetic interactions of an inorganic–organic hybrid radical-functionalized Mn-Anderson cluster

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Abstract

A family of six polyoxometalate-based magnetic compounds were synthesized by anchoring N-oxide type TEMPO radicals onto an Anderson type polyoxometalate cluster. The complexes were structurally characterised by single crystal X-ray diffraction and the intramolecular paramagnetic interactions between TEMPO radicals and Mn ions of the resulting hybrids were investigated in detail by electron paramagnetic resonance and the Evans NMR method.

Graphical abstract: Elucidating the paramagnetic interactions of an inorganic–organic hybrid radical-functionalized Mn-Anderson cluster

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Article information


Submitted
05 Dec 2020
Accepted
25 Jan 2021
First published
26 Jan 2021

This article is Open Access

Dalton Trans., 2021,50, 2350-2353
Article type
Communication

Elucidating the paramagnetic interactions of an inorganic–organic hybrid radical-functionalized Mn-Anderson cluster

C. Lin, M. Hutin, C. Busche, N. L. Bell, D. Long and L. Cronin, Dalton Trans., 2021, 50, 2350
DOI: 10.1039/D0DT04149A

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