Issue 48, 2021

The electron that breaks the catalyst's back – excited state dynamics in intermediates of molecular photocatalysts

Abstract

In situ spectroelectrochemical studies focussing on the Franck–Condon region and sub-ns electron transfer processes in Ru(II)-tpphz-Pt(II) based photocatalysts reveal that single-electron reduction effectively hinders intramolecular electron transfer between the photoexcited Ru chromophore and the Pt center.

Graphical abstract: The electron that breaks the catalyst's back – excited state dynamics in intermediates of molecular photocatalysts

Supplementary files

Article information

Article type
Paper
Submitted
01 Oct 2021
Accepted
25 Nov 2021
First published
25 Nov 2021

Phys. Chem. Chem. Phys., 2021,23, 27397-27403

The electron that breaks the catalyst's back – excited state dynamics in intermediates of molecular photocatalysts

C. Müller, I. Friedländer, B. Bagemihl, S. Rau and B. Dietzek-Ivanšić, Phys. Chem. Chem. Phys., 2021, 23, 27397 DOI: 10.1039/D1CP04498B

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