Chiral recognition coupled with chemometrics using boronate ensembles containing D–π–A cyanostilbenes

Kaede Kawaguchi; Ayana Moro; Soya Kojima; Yuji Kubo

doi:10.1039/D1CC05492A

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Chiral recognition coupled with chemometrics using boronate ensembles containing D–π–A cyanostilbenes†

Kaede Kawaguchi,^a Ayana Moro,^a Soya Kojima^a and Yuji Kubo

*^a

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^a Department of Applied Chemistry for Environment, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji, Tokyo, Japan

Abstract

Two types of boronic acid-appended D–π–A cyanostilbenes were synthesized to produce chiral boronate ensembles via dehydration with tartaric acid. The aggregation-induced high sensitivity and positional effect of the CN group on the emission properties allowed for chemometrics-coupled chiral recognition.

This article is part of the themed collection: Host-Guest Chemistry

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DOI: https://doi.org/10.1039/D1CC05492A
Article type: Communication
Submitted: 29 Sep 2021
Accepted: 12 Nov 2021
First published: 13 Nov 2021

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Chem. Commun., 2021,57, 12952-12955

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Chiral recognition coupled with chemometrics using boronate ensembles containing D–π–A cyanostilbenes

K. Kawaguchi, A. Moro, S. Kojima and Y. Kubo, Chem. Commun., 2021, 57, 12952 DOI: 10.1039/D1CC05492A

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Chemical Communications

Chiral recognition coupled with chemometrics using boronate ensembles containing D–π–A cyanostilbenes†

Abstract

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Chiral recognition coupled with chemometrics using boronate ensembles containing D–π–A cyanostilbenes

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