Issue 52, 2021

Rh(iii)-Catalyzed allylic C–H amidation of unactivated alkenes with in situ generated iminoiodinanes

Abstract

Rh(III)-catalyzed allylic C–H amidation of substituted alkenes with in situ generated iminoiodinanes is demonstrated. The presented protocol is compatible with differently functionalized unactivated terminal alkenes and internal alkenes. In terminal alkenes, branch selectivity was observed exclusively. Based on the detailed mechanistic investigation, a possible reaction mechanism involving the in situ generated π-allyl as well as metal–nitrene intermediates has been proposed.

Graphical abstract: Rh(iii)-Catalyzed allylic C–H amidation of unactivated alkenes with in situ generated iminoiodinanes

Supplementary files

Article information

Article type
Communication
Submitted
29 Apr 2021
Accepted
27 May 2021
First published
27 May 2021

Chem. Commun., 2021,57, 6428-6431

Rh(III)-Catalyzed allylic C–H amidation of unactivated alkenes with in situ generated iminoiodinanes

P. Sihag and M. Jeganmohan, Chem. Commun., 2021, 57, 6428 DOI: 10.1039/D1CC02283K

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