Issue 26, 2021
From the journal:

Chemical Communications

Copper-catalyzed borylative aminomethylation of C–C double and triple bonds with N,O-acetal†

Xianfan Qiu,a   Liugen Xu,a   Shuxia Wang,a   Ying Dai,a   Yunqiu Feng,a   Chang Gonga  and  Chuanzhou Tao ORCID logo *a  

* Corresponding authors

a School of Environmental and Chemical Engineering, Jiangsu Ocean University, Lianyungang 222005, China
E-mail: taocz@jou.edu.cn

Abstract

A copper-catalyzed borylaminomethylation of multiple carbon–carbon bonds with N,O-acetal and bis(pinacolato)diboron has been disclosed that offers efficient and expedient access to γ-amino boronates. The products contain a valuable amine and boronate, which are amenable to further elaboration, and have versatile synthetic utilities.

Graphical abstract: Copper-catalyzed borylative aminomethylation of C–C double and triple bonds with N,O-acetal

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Article information

DOI
https://doi.org/10.1039/D1CC00093D
Article type
Communication
Submitted
06 Jan 2021
Accepted
23 Feb 2021
First published
23 Feb 2021

Chem. Commun., 2021,57, 3279-3282

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Copper-catalyzed borylative aminomethylation of C–C double and triple bonds with N,O-acetal

X. Qiu, L. Xu, S. Wang, Y. Dai, Y. Feng, C. Gong and C. Tao, Chem. Commun., 2021, 57, 3279 DOI: 10.1039/D1CC00093D

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