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Synthesis and electron-transport properties of a stable antiaromatic NiII norcorrole with the smallest meso-substituent

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Abstract

meso-Dimethylnorcorrole NiII complex exhibited enough stability under ambient conditions despite the distinct antiaromaticity. The small methyl substituents realized a dense and long-range π-stacking in its solid state, which resulted in the superior electron-transporting ability to previously reported NiII norcorroles.

Graphical abstract: Synthesis and electron-transport properties of a stable antiaromatic NiII norcorrole with the smallest meso-substituent

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Article information


Submitted
08 Sep 2020
Accepted
23 Sep 2020
First published
25 Sep 2020

Dalton Trans., 2020, Advance Article
Article type
Communication

Synthesis and electron-transport properties of a stable antiaromatic NiII norcorrole with the smallest meso-substituent

S. Ukai, Y. H. Koo, N. Fukui, S. Seki and H. Shinokubo, Dalton Trans., 2020, Advance Article , DOI: 10.1039/D0DT03143G

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