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Issue 29, 2020
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Study and modular synthesis of unsymmetrical bis(phosphino)pyrrole ligands

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Abstract

We report the facile and modular synthesis of unsymmetrical 1,2-bis(phosphino)pyrrole ligands and their coordination chemistry. These ligands offer a promising alternative to their 1,2-bis(phosphino)benzene congeners, retaining a similar steric profile with attenuated electron donation. Proof-of-principle application of a bis(phosphino)pyrrole ligand in a nickel-catalyzed C–N cross-coupling reaction under mild conditions is demonstrated.

Graphical abstract: Study and modular synthesis of unsymmetrical bis(phosphino)pyrrole ligands

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Article information


Submitted
09 Jun 2020
Accepted
13 Jul 2020
First published
14 Jul 2020

Dalton Trans., 2020,49, 9957-9960
Article type
Communication

Study and modular synthesis of unsymmetrical bis(phosphino)pyrrole ligands

H. D. Fokwa, J. F. Vidlak, S. C. Weinberg, I. D. Duplessis, N. D. Schley and M. W. Johnson, Dalton Trans., 2020, 49, 9957
DOI: 10.1039/D0DT02063J

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