Issue 29, 2020
From the journal:

Dalton Transactions

Dense π-stacking of flexible ligands fixed in interpenetrating Zn(ii) MOF exhibiting long-lasting phosphorescence and efficient carrier transport†

Mei-Li Zhang, ORCID logo a   Ye Bai,a   Xiao-Gang Yang, ORCID logo *b   Yan-Jin Zheng,a   Yi-Xia Ren, ORCID logo a   Ji-Jiang Wang, ORCID logo a   Min-Le Han,b   Fei-Fei Lic  and  Lu-Fang Ma ORCID logo *b  

* Corresponding authors

a Department of Chemistry and Chemical Engineering, Yan'an University, Laboratory of New Energy & New Function Materials, Yan′an, Shaanxi 716000, P. R. China

b College of Chemistry and Chemical Engineering, Luoyang Normal University, Henan Province Function-Oriented Porous Materials Key Laboratory, Luoyang 471934, P. R. China

c College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, P. R. China
E-mail: mazhuxp@126.com

Abstract

Three-fold interpenetrating Zn(II) MOF with the dense π-stacking of flexible ligands exhibit long-lived phosphorescence emission up to 91 ms at room temperature. Photoelectric measurements show efficient electro-hole separation based on the long lifetime of triplet state exciton.

Graphical abstract: Dense π-stacking of flexible ligands fixed in interpenetrating Zn(ii) MOF exhibiting long-lasting phosphorescence and efficient carrier transport

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Article information

DOI
https://doi.org/10.1039/D0DT01810D
Article type
Communication
Submitted
19 May 2020
Accepted
04 Jul 2020
First published
06 Jul 2020

Dalton Trans., 2020,49, 9961-9964

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Dense π-stacking of flexible ligands fixed in interpenetrating Zn(II) MOF exhibiting long-lasting phosphorescence and efficient carrier transport

M. Zhang, Y. Bai, X. Yang, Y. Zheng, Y. Ren, J. Wang, M. Han, F. Li and L. Ma, Dalton Trans., 2020, 49, 9961 DOI: 10.1039/D0DT01810D

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