Tris(ferrocenylmethidene)sumanene: synthesis, photophysical properties and applications for efficient caesium cation recognition in water

Artur Kasprzak; Agata Kowalczyk; Agata Jagielska; Barbara Wagner; Anna M. Nowicka; Hidehiro Sakurai

doi:10.1039/D0DT01506G

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Tris(ferrocenylmethidene)sumanene: synthesis, photophysical properties and applications for efficient caesium cation recognition in water†

Artur Kasprzak,

*^a Agata Kowalczyk,

^b Agata Jagielska,

^c Barbara Wagner,

^c Anna M. Nowicka

^b and Hidehiro Sakurai

Author affiliations

* Corresponding authors

^a Faculty of Chemistry, Warsaw University of Technology, Noakowskiego Str. 3, 00-664 Warsaw, Poland
E-mail: akasprzak@ch.pw.edu.pl

^b Faculty of Chemistry, University of Warsaw, Pasteura Str. 1, 02-093 Warsaw, Poland

^c Biological and Chemical Research Centre, Faculty of Chemistry, University of Warsaw, Zwirki i Wigury Str. 101, PL-02-093 Warsaw, Poland

^d Division of Applied Chemistry Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

Abstract

The synthesis of a sumanene derivative bearing three ferrocenyl substituents is presented. This conjugated compound is solution-processable, shows red-light emission with high fluorescence quantum yield and can be used for the construction of the first buckybowl-based sensor for the selective and effective recognition of caesium cations (Cs⁺) in aqueous solution.

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Article information

DOI: https://doi.org/10.1039/D0DT01506G
Article type: Paper
Submitted: 24 Apr 2020
Accepted: 15 Jun 2020
First published: 15 Jun 2020
This article is Open Access

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Dalton Trans., 2020,49, 9965-9971

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Tris(ferrocenylmethidene)sumanene: synthesis, photophysical properties and applications for efficient caesium cation recognition in water

A. Kasprzak, A. Kowalczyk, A. Jagielska, B. Wagner, A. M. Nowicka and H. Sakurai, Dalton Trans., 2020, 49, 9965 DOI: 10.1039/D0DT01506G

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Dalton Transactions

Tris(ferrocenylmethidene)sumanene: synthesis, photophysical properties and applications for efficient caesium cation recognition in water†

Abstract

Supplementary files

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Tris(ferrocenylmethidene)sumanene: synthesis, photophysical properties and applications for efficient caesium cation recognition in water

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