Copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids

Shuo Yang; Pin Gao; Meng-Ting Suo; Shu-Xin Gao; Xin-Hua Duan; Li-Na Guo

doi:10.1039/D0CC04439C

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Copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids†

Shuo Yang,^a Pin Gao,*^a Meng-Ting Suo,^a Shu-Xin Gao,^a Xin-Hua Duan

^ab and Li-Na Guo

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, School of Chemistry, Xi’an Key Laboratory of Sustainable Energy Material Chemistry, and MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi’an Jiaotong University, Xi’an 710049, China
E-mail: guoln81@xjtu.edu.cn, gaopin@xjtu.edu.cn

^b State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China

Abstract

A mild copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids is described. This three-component protocol provides a straightforward approach to the remote keto-functionalized 1,1-diarylmethane derivatives. A radical pathway initiated by C–C bond cleavage is proposed for this tandem reaction.

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Article information

DOI: https://doi.org/10.1039/D0CC04439C
Article type: Communication
Submitted: 27 Jun 2020
Accepted: 03 Aug 2020
First published: 06 Aug 2020

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Chem. Commun., 2020,56, 10714-10717

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Copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids

S. Yang, P. Gao, M. Suo, S. Gao, X. Duan and L. Guo, Chem. Commun., 2020, 56, 10714 DOI: 10.1039/D0CC04439C

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Chemical Communications

Copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids†

Abstract

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Copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids

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