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Issue 18, 2019, Issue in Progress
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Synthesis of new polyesters by acyclic diene metathesis polymerization of bio-based α,ω-dienes prepared from eugenol and castor oil (undecenoate)

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Abstract

Synthesis of new polyesters by acyclic diene metathesis (ADMET) polymerization of α,ω-diene, 4-allyl-2-methoxyphenyl 10-undecenoate (M1), prepared from bio-renewable eugenol and castor oil (undecenoate), have been demonstrated. Ruthenium-carbene (called second generation Grubbs) catalyst afforded polymers with unimodal molecular weight distributions (Mn = 12 700, Mw/Mn = 1.85). The polymerization in the presence of a triarm cross-linker, 5-formylbenzene-1,2,3-triyl tris(undec-10-enoate), also afforded polymers with certain uniform network structures.

Graphical abstract: Synthesis of new polyesters by acyclic diene metathesis polymerization of bio-based α,ω-dienes prepared from eugenol and castor oil (undecenoate)

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Article information


Submitted
10 Feb 2019
Accepted
27 Mar 2019
First published
02 Apr 2019

This article is Open Access

RSC Adv., 2019,9, 10245-10252
Article type
Paper

Synthesis of new polyesters by acyclic diene metathesis polymerization of bio-based α,ω-dienes prepared from eugenol and castor oil (undecenoate)

D. Le, C. Samart, S. Kongparakul and K. Nomura, RSC Adv., 2019, 9, 10245
DOI: 10.1039/C9RA01065C

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