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Issue 4, 2019
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Platinum free thermally curable siloxanes for optoelectronic application – synthesis and properties

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Abstract

Polysiloxanes for applications in the area of optical devices are usually based on two-component platinum catalysed cross-linked materials. Here we report the synthesis and properties of a novel one-component siloxane that can be thermally cured showing similar tailorable properties like commercially available encapsulation systems without using a noble metal catalyst. The pre-curing material is formed by an acid catalysed condensation reaction of trialkoxysilanes (TAS), dialkoxysilanes (DAS) and alkoxy-terminated polysiloxanes. NMR analysis of the formed polymeric compounds reveal that the materials are partially cross-linked gels. The obtained compounds can be thermally cured and consolidated at temperatures between 160 and 200 °C. Depending on the composition a tuneable hardness in between 50–90 Shore A, refractive indices of 1.494–1.505, as well as high temperature stabilities up to 443 °C were obtained. The high thermal- and photostability, the high transparency, as well as the tailorable refractive index makes these materials to ideal systems for optoelectronic applications. Investigations under increased temperatures and high-density illumination reveal that the material can withstand conditions, which are typical for high-performance light emitting diodes (LED).

Graphical abstract: Platinum free thermally curable siloxanes for optoelectronic application – synthesis and properties

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Publication details

The article was received on 28 Nov 2018, accepted on 05 Jan 2019 and first published on 17 Jan 2019


Article type: Paper
DOI: 10.1039/C8RA09801H
RSC Adv., 2019,9, 2205-2216
  • Open access: Creative Commons BY-NC license
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    Platinum free thermally curable siloxanes for optoelectronic application – synthesis and properties

    N. Steinbrück, S. Pohl and G. Kickelbick, RSC Adv., 2019, 9, 2205
    DOI: 10.1039/C8RA09801H

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