A surface carbonization strategy towards MoS2 microspheres with enhanced electrochemical hydrogen evolution activity

Abstract

Surface engineering is of great importance to rationally change the catalyst's surface structure and provide insights into the surface reactivity when developing high-efficiency and earth-abundant catalysts for electrocatalytic water splitting. Herein, nitrogen-doped carbon (NC) nanoparticle-decorated MoS₂ is successfully constructed via a surface carbonization strategy simply by sintering MoS₂ microspheres and dicyandiamide (DCDA), which generates tiny NC nanoparticles on the MoS₂ surface. The presence of NC nanoparticles on MoS₂ not only facilitates the charge transfer and reaction kinetics but also promotes the hydrogen adsorption during the electrocatalytic hydrogen evolution reaction (HER) process, thereby endowing the catalyst with a much lower overpotential and a higher current density in comparison to pristine MoS₂. This work indicates that the surface carbonization strategy provides a promising way for designing highly active electrocatalysts in terms of surface structure engineering.