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Issue 2, 2019
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A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

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Abstract

The [PdCl4]2− palladium complex has been immobilized on a polystyrene-type resin loaded with pincer-type imidazolium ionic tag binding sites. The catalytic system (Pd(II)-POLI-TAG) has proved to be highly active in the definition of an efficient protocol for the Heck–Mizoroki coupling reaction under batch and flow conditions. Importantly, it is shown to be highly robust in combination with a safe non-toxic reaction medium, i.e. biomass-derived GVL, since it could be reused for multiple runs without significantly losing its activity.

Graphical abstract: A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

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Publication details

The article was received on 14 Oct 2018, accepted on 13 Dec 2018 and first published on 21 Dec 2018


Article type: Paper
DOI: 10.1039/C8GC03228A
Green Chem., 2019,21, 355-360

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    A tailored polymeric cationic tag–anionic Pd(II) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

    H. Mahmoudi, F. Valentini, F. Ferlin, L. A. Bivona, I. Anastasiou, L. Fusaro, C. Aprile, A. Marrocchi and L. Vaccaro, Green Chem., 2019, 21, 355
    DOI: 10.1039/C8GC03228A

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