Rare metal-ion metathesis of a tetrahedral Zn(II) core of a noncentrosymmetric (3,4)-connected 3D MOF

Li-Wei Lee; Ya-Chuan Kao; Mei-Ying Chung; Bor-Chen Chang; Gene-Hsiang Lee; Shie-Ming Peng; Chih-Min Wang; Yen-Hsiang Liu; Sheng-Long Lee; Kuang-Lieh Lu

doi:10.1039/C8DT04472D

Rare metal-ion metathesis of a tetrahedral Zn(ii) core of a noncentrosymmetric (3,4)-connected 3D MOF†

Li-Wei Lee,^ab Ya-Chuan Kao,^a Mei-Ying Chung,^a Bor-Chen Chang,^c Gene-Hsiang Lee,^d Shie-Ming Peng,^d Chih-Min Wang,

*^e Yen-Hsiang Liu,*^f Sheng-Long Lee*^b and Kuang-Lieh Lu*^ab

Author affiliations

* Corresponding authors

^a Institute of Chemistry, Academia Sinica, Taipei 115, Taiwan
E-mail: kllu@gate.sinica.edu.tw

^b Institute of Materials Science and Engineering, National Central University, Taoyuan 320, Taiwan
E-mail: shenglon@cc.ncu.edu.tw

^c Department of Chemistry, National Central University, Taoyuan 320, Taiwan

^d Department of Chemistry, National Taiwan University, Taipei 107, Taiwan

^e Department of Bioscience and Biotechnology, National Taiwan Ocean University, Keelung 202, Taiwan
E-mail: twcmwang@gmail.com, cmwang@ntou.edu.tw

^f Department of Chemistry, Fu Jen Catholic University, Taipei 242, Taiwan
E-mail: chem2022@mails.fju.edu.tw

Abstract

An SHG-active noncentrosymmetric (3,4)-connected Zn(II)–organic framework, {[Zn₂(4-abpt)(3,4-pydc)₂]·2DMAc·3MeOH·H₂O}_n (1-Zn), was synthesized using a mixed-ligand system. The 1-Zn framework undergoes metal metathesis, with the complete exchange of the tetrahedrally coordinated Zn^II ions with Cu^II ions while retaining the integrity of the network.

Dalton Transactions

Rare metal-ion metathesis of a tetrahedral Zn(ii) core of a noncentrosymmetric (3,4)-connected 3D MOF†

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Rare metal-ion metathesis of a tetrahedral Zn(II) core of a noncentrosymmetric (3,4)-connected 3D MOF

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