Conversion of haloform to carbonate by iridium N-heterocyclic carbene complexes and silver(I) oxide

Andrew C. Marr; Patrick J. Morgan; Graham C. Saunders; Hayden P. Thomas

doi:10.1039/C8DT04456B

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Conversion of haloform to carbonate by iridium N-heterocyclic carbene complexes and silver(i) oxide†

Andrew C. Marr,

^a Patrick J. Morgan,^a Graham C. Saunders

*^b and Hayden P. Thomas^b

Author affiliations

* Corresponding authors

^a School of Chemistry and Chemical Engineering, Queen's University Belfast, David Keir Building, Belfast BT9 5AG, UK

^b School of Science, University of Waikato, Hamilton 3240, New Zealand
E-mail: graham.saunders@waikato.ac.nz

Abstract

The reaction between haloform, the complexes [Cp*IrCl₂(κC-MeNC₃H₂NCH₂Ar)] (Ar = C₆H₃F₂-2,6, C₆H₃F-2-Cl-6, C₆H₃Me₂-2,6) and silver(I) oxide proceeded by carbon–halogen bond fission to yield the carbonate complexes [Cp*Ir(κ²O-CO₃)(κC-MeNC₃H₂NCH₂Ar)].

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Article information

DOI: https://doi.org/10.1039/C8DT04456B
Article type: Communication
Submitted: 09 Nov 2018
Accepted: 07 Jan 2019
First published: 08 Jan 2019

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Dalton Trans., 2019,48, 1947-1949

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Conversion of haloform to carbonate by iridium N-heterocyclic carbene complexes and silver(I) oxide

A. C. Marr, P. J. Morgan, G. C. Saunders and H. P. Thomas, Dalton Trans., 2019, 48, 1947 DOI: 10.1039/C8DT04456B

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Dalton Transactions

Conversion of haloform to carbonate by iridium N-heterocyclic carbene complexes and silver(i) oxide†

Abstract

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Conversion of haloform to carbonate by iridium N-heterocyclic carbene complexes and silver(I) oxide

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