Issue 81, 2019
From the journal:

Chemical Communications

Spin-crossover iron(ii) complex showing thermal hysteresis around room temperature with symmetry breaking and an unusually high T(LIESST) of 120 K†

Víctor García-López,a   Mario Palacios-Corella,a   Salvador Cardona-Serra, ORCID logo a   Miguel Clemente-León ORCID logo *a  and  Eugenio Coronado ORCID logo a  

* Corresponding authors

a Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, Catedrático José Beltrán 2, 46980 Paterna, Spain
E-mail: miguel.clemente@uv.es

Abstract

We report a Fe(II) complex based on 4′,4′′ carboxylic acid disubstituted dipyrazolylpyridine that shows a spin-crossover close to room temperature associated to a crystallographic phase transition and the LIESST effect with a high T(LIESST) of 120 K.

Graphical abstract: Spin-crossover iron(ii) complex showing thermal hysteresis around room temperature with symmetry breaking and an unusually high T(LIESST) of 120 K

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Article information

DOI
https://doi.org/10.1039/C9CC05988A
Article type
Communication
Submitted
01 Aug 2019
Accepted
12 Sep 2019
First published
13 Sep 2019

Chem. Commun., 2019,55, 12227-12230

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Spin-crossover iron(II) complex showing thermal hysteresis around room temperature with symmetry breaking and an unusually high T(LIESST) of 120 K

V. García-López, M. Palacios-Corella, S. Cardona-Serra, M. Clemente-León and E. Coronado, Chem. Commun., 2019, 55, 12227 DOI: 10.1039/C9CC05988A

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