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Issue 31, 2019
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Ruthenium(ii)-catalysed direct synthesis of ketazines using secondary alcohols

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Abstract

Direct one-pot synthesis of ketazines from secondary alcohols and hydrazine hydrate catalyzed by a ruthenium pincer complex is reported, which proceeds through O–H bond activation of secondary alcohols via amine–amide metal–ligand cooperation in the catalyst. Remarkably, liberated molecular hydrogen and water are the only byproducts.

Graphical abstract: Ruthenium(ii)-catalysed direct synthesis of ketazines using secondary alcohols

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Supplementary files

Article information


Submitted
18 Feb 2019
Accepted
21 Mar 2019
First published
29 Mar 2019

Chem. Commun., 2019,55, 4542-4545
Article type
Communication

Ruthenium(II)-catalysed direct synthesis of ketazines using secondary alcohols

J. Kishore, S. Thiyagarajan and C. Gunanathan, Chem. Commun., 2019, 55, 4542
DOI: 10.1039/C9CC01383K

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