Y8O(OH)15(CO3)3Cl: an excellent short-wave UV nonlinear optical material exhibiting an infrequent three-dimensional inorganic cationic framework

Yiting Zhang; Ying Long; Xuehua Dong; Lei Wang; Ling Huang; Hongmei Zeng; Zhien Lin; Xin Wang; Guohong Zou

doi:10.1039/C9CC00581A

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Y₈O(OH)₁₅(CO₃)₃Cl: an excellent short-wave UV nonlinear optical material exhibiting an infrequent three-dimensional inorganic cationic framework†

Yiting Zhang,^a Ying Long,^a Xuehua Dong,^a Lei Wang,^b Ling Huang,^b Hongmei Zeng,^a Zhien Lin,

^a Xin Wang^a and Guohong Zou

*^a

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* Corresponding authors

^a College of Chemistry, Sichuan University, Chengdu, P. R. China
E-mail: zough@scu.edu.cn

^b College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, P. R. China

Abstract

A novel compound with four mixed anions, Y₈O(OH)₁₅(CO₃)₃Cl, exhibiting an infrequent three-dimensional (3-D) inorganic cationic framework, has been successfully designed and synthesized by introducing π-conjugated planar triangular CO₃ groups and chloride anions into a rare earth oxide system, which exhibits good balance among its wide UV transmission range, large second harmonic generation (SHG) coefficient and suitable birefringence to meet the phase-matching condition, indicating that the titled compound is a promising short-wave UV nonlinear optical material.

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Article information

DOI: https://doi.org/10.1039/C9CC00581A
Article type: Communication
Submitted: 22 Jan 2019
Accepted: 25 Mar 2019
First published: 25 Mar 2019

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Chem. Commun., 2019,55, 4538-4541

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Y₈O(OH)₁₅(CO₃)₃Cl: an excellent short-wave UV nonlinear optical material exhibiting an infrequent three-dimensional inorganic cationic framework

Y. Zhang, Y. Long, X. Dong, L. Wang, L. Huang, H. Zeng, Z. Lin, X. Wang and G. Zou, Chem. Commun., 2019, 55, 4538 DOI: 10.1039/C9CC00581A

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